권수민 Su-min Kwon , 천승민 Seung-min Cheon , 이채은 Chae-eun Lee , 황선진 Sun-jin Hwang
DOI:10.9786/kswm.2026.43.1.14
Abstract
CO₂ absorption, a key carbon capture and utilization (CCU) technology for achieving carbon neutrality, requires large amounts of freshwater, thereby limiting its sustainability. This study presents a fundamental investigation aimed at developing Seawater-Based Carbon Capture (SBCC) technology through a comparative analysis of CO₂ absorption characteristics in freshwater and seawater. CO₂ absorption amount and capacity were evaluated in artificial seawater using NaOH as the absorbent, with pH maintained between 10 and 13. Additionally, changes in Mg2+ and Ca2+ concentrations were analyzed to assess the precipitation of MgCO₃ and CaCO₃ during CO₂ absorption in seawater. Seawater exhibited higher CO₂ absorption amounts than freshwater at all pH levels, primarily due to enhanced CO₂ dispersion resulting from salinity, which increased the specific surface area available for absorption. At pH 12, the total CO₂ absorption amount in seawater was approximately 24% higher than that in freshwater. CO₃2- precipitation occurred during CO₂ absorption in artificial seawater. Above pH 11, precipitates, presumed to be Na2CO₃, increased due to the common-ion effect of Na+ and the greater NaOH demand required to maintain the elevated pH. At pH 13, CO₃2⁻ precipitates accounted for approximately 34% of the total absorbed CO₂, raising concerns about potential clogging in future SBCC system operations. Therefore, considering both CO₂ absorption efficiency and precipitation behavior, a pH around 12 appears optimal for SBCC operation. However, at the same pH, seawater exhibited a relatively lower absorption capacity than freshwater, likely due to increased NaOH consumption caused by CO₃2⁻ and OH⁻ precipitation reactions with Mg2+ and Ca2+. In conclusion, while seawater offers advantages in CO₂ absorption, further research is necessary to control precipitation and enhance absorption capacity to advance SBCC technology.
Key Words
Seawater, CO₂ absorption, Common-ion effect, Clogging